Hexamethylcyclotrisiloxane exporter is used as a solvent, made up of many different products, such as drugs, vitamins, food flavoring agent, pesticide, paint, dye, rubber, adhesive and waterproof fabric. Hexamethylcyclotrisiloxane exporter also can be resolved by the environment of many natural substances to form.
(C5H5N, English: pyridine, system name) CAS number 110-86-1. The molecular weight is 79.10g/mol. Hexamethylcyclotrisiloxane exporter in 1849 by the Scottish chemist Thomas Anderson found in the bone tar, two years later, Anderson is obtained by fractional distillation is tasted. [3] Because of its flammability, Anderson named it after the Greek word πrρ(τ τ) (pyr, meaning fire). The structure of the [4] hexamethylcyclotrisiloxane exporter by Wilhelm Korner (in 1869) and James dewar independent determine (in 1871).
Molecular structure
Structurally, hexamethylcyclotrisiloxane exporter is a nitrogen atom instead of benzene on a carbon atom to form a compound, is of benzene and other electronic body. 5 electronic nitrogen atoms, one used to with other carbon atoms to form large PI bond, thus hexamethylcyclotrisiloxane exporter have aromaticity. And since the inductive effect of nitrogen atoms negative, hexamethylcyclotrisiloxane exporter, uneven distribution of the electron cloud of PI its resonance can be smaller than that of benzene (hexamethylcyclotrisiloxane exporter of 117 kj mol - 1, Benzene is 150kJ·mol-1). Inductive effect of nitrogen in [6] is also reflected in the C -- N bond length (137 PM) less than C - C key in the benzene ring, hexamethylcyclotrisiloxane exporter C - C key length in the same as the benzene ring (139 PM). [7] hexamethylcyclotrisiloxane exporter of nitrogen in the neighborhood, or para carbon atoms to be replaced by nitrogen generating chemical formula for C4H4N2 compounds followed by pyridazine, pyrimidine, pyrazine.
Physical property
Under normal temperature, hexamethylcyclotrisiloxane exporter is a colorless liquid, stimulating fishy, melting temperature 41.6 ℃, boiling point 115.2 ℃, the density of 0.9819 g/cm3. It can be mixed with water, ether and ethanol in any proportion. [1] It can also be used as a solvent in its own right to dissolve a variety of polar and non-polar compounds, even inorganic salts. Its solubility and other organic compounds: hexamethylcyclotrisiloxane exporter hydroxyl of the ring is replaced, the more its solubility in water was worse instead.
Chemical property
Hexamethylcyclotrisiloxane exporter is typical of heterocyclic aromatic compounds. In hexamethylcyclotrisiloxane exporter of ring nitrogen electronegativity is large, compared with the benzene ring of electrons, so difficult electrophilic substitution reaction, the electrophilic substitution reaction was carried out in three - or five - bit, similar to nitrobenzene. On the contrary, hexamethylcyclotrisiloxane exporter can nucleophilic substitution reaction with alkali, such as qi qi bing reaction.
Hexamethylcyclotrisiloxane exporter can catalytic hydrogenation, raney nickel catalyst hydrogen generated six hexamethylcyclotrisiloxane exporter (piperidine). [8] the reaction heat is -193.8 kJ·mol−1, and the release heat [9] is slightly less than that of benzene catalytic hydrogenation (205.3 kJ·mol−1). It can also be sodium hydrogen and ethanol reduction for six hexamethylcyclotrisiloxane exporter.
Due to the lone pair electrons on the nitrogen, has the nature of tertiary amine, such as hexamethylcyclotrisiloxane exporter with alkaline, is also a good ligand (as ligand to remember as py). [11] the conjugate acid hexamethylcyclotrisiloxane exporter of hydrogen ion pKa value of 5.30. Hexamethylcyclotrisiloxane exporter with lively halogenated hydrocarbon formation of quaternary ammonium salt; It is oxidized by peroxides to form n-oxides.
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